Studies of the Electron Transfer System

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Studies on the Electron Transfer System

The study of the terminal electron transfer system has been approached essentially in two ways. The first approach has been by way of the study of electron transfer in intact cells and in respiratory chain particles such as mitochrondria; it can best be exemplified by the studies of Chance and Williams (1). The second approach, which has been used in this laboratory, involves fragmentation of m...

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Electron-transfer studies of a peroxide dianion.

A peroxide dianion (O2(2-)) can be isolated within the cavity of hexacarboxamide cryptand, [(O2)⊂mBDCA-5t-H6](2-), stabilized by hydrogen bonding but otherwise free of proton or metal-ion association. This feature has allowed the electron-transfer (ET) kinetics of isolated peroxide to be examined chemically and electrochemically. The ET of [(O2)⊂mBDCA-5t-H6](2-) with a series of seven quinones,...

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Studies on the Electron Transfer System. Lxii. the Reaction of Cytochrome Oxidase with Carbon Monoxide.

The participation of molecular oxygen in biological oxidations is catalyzed by an enzyme which has been called-a variety of names starting with Atmungsfemzent by Warburg (18) to the currently employed term of cytochrome oxidase proposed by Keilin and Hartree (11). Presumably the enzyme functions by first combining with molecular oxygen and then becoming oxidized by it. As first shown by Warburg...

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ژورنال

عنوان ژورنال: Journal of Biological Chemistry

سال: 1961

ISSN: 0021-9258

DOI: 10.1016/s0021-9258(19)76405-9